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Information × Registration Number 0224U033210, (0119U102727) , R & D reports Title Stable carbenes of the heterocyclic and acyclic series. Catalytic properties in the reactions of nucleophilic substitution of halogen in haloarenes. popup.stage_title Cтабільні карбени гетероциклічного та ациклічного рядів. Каталітичні властивості в реакціях нуклеофільного заміщення галогену в галоаренах Head Korotkikh Mykola I., Доктор хімічних наук Registration Date 21-12-2024 Organization Institute of Organic Chemistry NAS of Ukraine popup.description1 The purpose of the research is to study the catalytic properties of stable carbenes of heterocyclic and acyclic series and their complexes with transition- and p-metals (high-base and high electron-donating mesoionic, ylidic, superbasic, cationic, sterically developed carbenes) in organic reactions (hydrohalogenation, functiondehalogenation, reduction of multiple bonds, oxidation of alcohols, condensation, transesterification). popup.description2  The catalytic properties of stable heterocyclic and acyclic carbenes and their complexes with transition and p-metals (highly basic and highly electron-donating - mesoionic, ylide, superbasic, cationic, sterically developed carbenes) in organic reactions (hydrodehalogenation, functional dehalogenation, reduction of multiple bonds, oxidation alcohols, condensations, transesterification). Applied research methods are synthetic, analytical (elemental analysis, titrimetric methods), spectral (1H, 13C NMR, IR, UV spectroscopy), mass spectrometry, X-ray structural analysis). The relevance of the work is related to the prospects of carbenes and their derivatives as catalysts of organic reactions. Based on carbenes of a new type, new highly effective catalysts for a number of organic reactions for technologies of "green" chemistry (reduction, oxidation, coupling, nucleophilic substitution, etc.) were obtained, and chiral compounds were obtained. Product Description popup.authors Korotkikh Mykola I. Sabierov Vahiz Sh. popup.nrat_date 2024-12-21 Close