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Information × Registration Number 0225U003560, (0122U001961) , R & D reports Title Chemical design of multifunctional coordination compounds and bistable supramolecular materials popup.stage_title Узагальнення результатів досліджень та надання рекомендацій для отримання нових мультифункціональних сполук та бістабільних супрамолекулярних матеріалів. Head Frytskyi Ihor O., Доктор хімічних наук Registration Date 14-07-2025 Organization Taras Shevchenko National University of Kyiv popup.description1 Synthesis of FeII compounds based on monodentant and polydentate bridge ligands with predictable types of supramolecular interactions, which determine controlled phase-labile behavior and spincrossover, as well as coordination metal-organic framework polymers such as Hoffman clathrates, absorbable molecules; synthesis of mononuclear and polymeric crystalline compounds with high-valence states of transition metals, study of their magnetic, optical and catalytic properties; establishing the laws of the relationship between the molecular and supramolecular structure of metal complexes and the development on this basis of original scientifically sound approaches to creating a new generation of bistable and catalytic compounds. popup.description2  The project is aimed at obtaining new functionalized ligand systems and coordination compounds of transition metals with specified or tunable optical, magnetic and catalytic properties, the control of the functional activity of which is achieved through programming of supramolecular interactions. The goal of the project is to synthesize Fe(II) compounds based on monodentate and polydentate bridging ligands with predictable types of supramolecular interactions that cause controlled phase-labile behavior and spin-crossover, coordination metal-organic framework polymers capable of absorbing/releasing small molecules; synthesis of mononuclear and polymeric crystalline compounds with high-valence states of transition metals, study of their magnetic, optical and catalytic properties; establishing the patterns of the relationship between the molecular and supramolecular structure of metal complexes and developing on this basis original scientifically sound approaches to the creation of a new generation of bistable and catalytic compounds. The idea of the project is to develop supramolecular principles for obtaining metal complexes with controlled bistable and photo- and electrocatalytic activity. The working hypothesis of the project is based on the assumption of the dominant influence of the molecular structure of the ligand and the molecular environment and the possibility of its "programming" to control the macroscopic properties and the corresponding spectrum of physicochemical characteristics of compounds. Product Description popup.authors Babik Yurii S. Vynohradov Oleksandr S. Hiiuk Volodymyr M. Kucheriv Olesia I. Plutenko Maksym O. Serediuk Maksym L. Tsapiuk Halyna H. popup.nrat_date 2025-07-14 Close