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Information × Registration Number 0306U001548, 0104U000658 , R & D reports Title Phase equilibriums solid - liquid in systems on basis of polyethyleneglycols popup.stage_title Міжчасткові взаємодії і процеси розчинності і сольватація в двійних змішаних розчинниках на основі поліктиленглюколів Head Krasnopyrova Alla Petrovna, Registration Date 20-04-2006 Organization Kharkov National University named after V.N.Karazin popup.description2 The purpose of work - research of the general and specific laws phase equations solids (caesium perchlorat) - solution (water - PEG?600 and water - PEG?1500) and substantiation of a choice of structure of new systems for radionuclide treatment and distilation from liquid environments. Method of research - performance of work is carried out with use of modern radioanalytical methods (radionuclides X-ray fluorescent the analysis - RRFA and a method of radioactive indicators), of some physical and chemical metods. Key words - polyethyleneglycols, caesium perchlorat, method of radioactive indicators.For the first time the polythermal data on density, dielectric permeability of caesium perchlorate in the mixed solvents water - PEG?600 and water - PEG?1500 in a wide interval of concentration of the mixed solvent are received.It is established, that in researched systems a number of processes is realized: formation оcsonic ions, formation of association PEG?WATER due to specific interactions between moleculesН2О and polar groups PEG. It is shown, that the complex and not additive behaviour of solubility and thermodynamics of dissolution of caesium perchlorate in water systems PEG is caused a lot of factors: character of interpartial interactions in the mixed solvent and specific donor?aczeptic interaction caesium cation with PEG. Product Description popup.authors popup.nrat_date 2020-04-02 Close