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Information × Registration Number 0307U001673, 0106U003101 , R & D reports Title Highly anisotropic conductors, superconductors and magnetics based on the sulfur - and vitrogencantaining compounds. popup.stage_title Cинтези КРС фульваленів (ЕТ, ТТF, ТМТТF та ТМТSF) з аніонами (Мdmid)2), де М-Mn,Fe,Co,Ni хімічними та електрохімічними методами Head Starodyb Vladimir Aleksandrovich, Registration Date 18-04-2007 Organization Kharkov national university named after V.N. Karazin popup.description2 Objects of research: New cation-radical salts (CRS) on a ЕТ basis, in particular, conducting complexes Ktn[M(dmid)2], where Kt - Li, Na, K, Rb, Cs; M - Mn, Fe, Co, Cu, Hg. The purpose of work: To receive new CRS on ЕТ basis and conducting complexes on their basis. Comprehensively to investigate their physical and chemical properties with the purpose of reception of new organic metals and superconductors with steadier metal basic condition. Synthesis of the given compounds and the received results of researches will enable to expand search of new stable quasi-three-dimensional organic metals and superconductors. Methods: modern methods of synthesis, IR-, UV- spectroscopy, X-ray analysis. The received results and novelty: For the first time are synthesized 61 complexes Ktn[M(dmid)2], where Kt - Li, Na, K, Rb, Cs; M - Mn, Fe, Co, Cu, Hg. Conducting and spectral properties ЕТ complexes are investigated. It is investigated the electrochemical behaviour of hydrogen-free ЕТ analogues. For a first time ARS dmid with unusual for dmid quasi-twodimensional conductivity are synthesized. This fact is confirmed by XRD data, electroresistivity measurements, magnetic susceptibility measurements and IR spectra. Some of the complexes have ability to melt without decomposition, that important for practical applications. Product Description popup.authors popup.nrat_date 2020-04-02 Close