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Information × Registration Number 0310U008265, 0106U001216 , R & D reports Title Co-ordination compounds of the dicarboxylic acids and its derivations popup.stage_title Координаційні сполуки дикарбонових кислот та їх похідних Head Shul'gin Victor, Registration Date 21-12-2010 Organization National Taurida V. Vernadsky University popup.description2 The spacer-armed binuclear complexes of copper(II) of a few types are synthesized and investigated. The first examples of spacer-armed treenuclear complexes of copper are synthesized and studied. Structure 12 complexes with different length and nature of hydrocarbon spacer are set from data of X-Ray analysis experiment. In the EPR spectrums of solutions of row of complexes with short spacer is observed izotropic signal from seven lines hyperfine structures due to the coupling of the uncoupled electrons with two equivalent nucleus of copper. The EPR-spectrums of binuclear complexes on the basis of acylhydrazones of aromatic dicarboxylic acids strongly depend on a temperature, that allows to say of supposition about the qualificatory role of dynamic effects in realization of mechanisms of exchange coupling through extensive hydrocarbon спейсер. Research of spacer-armed copper complexes is first executed by the methods of static magnetic susceptibility. Product Description popup.authors Гусев О.М. Конник О.В. Певзнер Н. С. Работягов К. В. Сарніт О.О. popup.nrat_date 2020-04-02 Close