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Information × Registration Number 0313U005120, 0107U010218 , R & D reports Title Kinetcs and Mechanism of New Catalytic and Radical Processes in Organic Synthesis and Nanocoatings Development popup.stage_title Дослідження радикальних реакцій циклізації в органічному синтезі моно- і біциклічних продуктів Head POKUTSA ALEXANDER PETROVICH, Registration Date 26-03-2013 Organization Physical Chemistry of Combustible Minerals Department Institute of Physical Organic Chemistry and Coal Chemistry of National Academy of Sciences of Ukraine popup.description2 The role of silyl radicals in the processes of reductive substitution, alkylation, and cyclization has been studied in the course of synthesis of complex products in the cascade-type reaction of intra- and intermolecular transformation with participation of aromatic and linear olefines with nitrogen-contained nucleophiles and elucidated the mechanism of such compounds influence. The influence of the ligands structure in Rh and Ru catalysts on selectivity of the aimed products formation (С-Н amination/aziridation ratio) during the amination of the allenicС-Н bonds in the course of construction of allene amides ( a- and b-unsaturated g-lactames) as well as the process conditions have been determined. Product Description popup.authors ЗАБОРОВСЬКИЙ Андрій Богданович МІДЯНА Галина Григорівна popup.nrat_date 2020-04-02 Close