Registration Number
0205U002428,
0102U001632
, R & D reports
Title
Physicochemical principles for the development of low-temperature antiozonants based on anchored metal-complex compounds
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Head
Rakitskaya T.L,
Registration Date
06-02-2005
Organization
Odessa I. I. Mechnikov's National University
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Subject of study - 3d metal complexes with acido and organic ligands and the kinetics of interaction of com-plexes, both dissolved and anchored to different support-ers, with both ozone and hydrogen peroxide.Objective of study - the development of theoretical prin-ciples for the prediction of catalytic activity of 3d metal complexes with acido and organic ligands in the decom-position of both ozone and hydrogen peroxide. Methods of research - spectral, physicochemical, kinetic, chemical, and quantum-chemical modeling of complex structure. As a result, the composition, structure, and catalytic activity of aerosil-anchored complexes of copper with Schiff bases have been determined. The kinetics of low-temperature interaction of ozone with supported hexamethylenetetra-mine has been studied. The interactions of sodium 5,5-diethylbarbiturate (NaL) with 3d metal salts and of 3d metal nitroprussides with thiosemicarbazide have been studied; and their catalytic activity in the hydrogen perox-ide decomposition reaction has been determined.
Product Description
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2020-04-03
