Intermediates of the transphase acilydation and the electron transfer at molecular oxygen reactions.
Shendrik Aleksander Nikolaevich,
Donetsk National University
Kinetics of phase-transfer activated amino acid ester aminolysis in two-phase systems of butanol-1/glicine buffer and chloroform/glicine buffer was studied under variation of nucleophil concentration in presence and absence of differed onium salts. Ion transport mechanism through phase boundary was proposed. Phase-transfer mechanism was determinated.