Search academic texts

Information × Registration Number 0210U004477, 0110U004013 , R & D reports Title Synthesis of chiral cage diamines and their usage in asymmetric catalisis popup.stage_title Head Shubina T.E., Registration Date 29-12-2010 Organization National Technical University of Ukraine "Kiev Polytechnic Institute" popup.description2 Report on research: 27 pages. 12 Fig., 3 tab., 1 addition, 28 sources. Objects of research - (2R, 3R)-bicyclo-[2.2.1]-heptane-2,3-diamine, (1) (2R, 3R)-bicyclo[2.2.1]heptane-2,3-diildimetylamine (2) and diamines of CS-tryshomocubanes (pentacyclo[5.4.0.02,6.03,10.05,9]undecane) (3-4) Aim of work - to develop efficient methods of synthesis cage diamines and their usage as catalysts in the reactions of Grignard, Suzuki, and Biginelli. Methods of synthesis of diamines 1-4 were developed and optimized in work, also reactions of Grignard, Suzuki, and Biginelli with these compounds as catalysts were investigated. ORGANIC SYNTHESIS,ASYMMETRIC CATALYSIS, QUANTUM-CHEMICAL CALCULATIONS, ENANTIOSELECTIVITY, REACTION OF GRIGNARD, SUZUKI, AND BIGINELLI. Product Description popup.authors Гайдай Олександр Васильович Левандовський Ігор Анатолійович Шарапа Дмитро Ігорович popup.nrat_date 2020-04-02 Close