Registration Number
0211U002205,
0109U002610
, R & D reports
Title
Copper(I) pi-complexes as potentional compounds with three-dimensional frameworks
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Head
Mys'kiv Marian Grygorovych,
Registration Date
25-01-2011
Organization
Ivan Franko National University of Lviv
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The 19 new crystalline copper(I) (and partial copper(II)) complexes with N,N'-diallylhydrazine-1,2-dicarbothioamide, 5-(allylthio)-1-phenyl-1H-tetrazole, 5-(allylthio)-1-(4-chlorophenyl)-1H-tetrazole, N,N-diallylhexamethylenimine cation, N-allylbenzotriazole, N,N,N,N',N',N'-hexaallylethylenediamminium dication, N-allyl-5-amino-1-phenyl-1H-1,2,3-triazole-4-carboxamide, N-allylmorpholinium cation, 3,3'-piperazine-1,4-diyldipropanenitrile, N-allyl-N,N,N',N'tetramethylethylene-diamminium cation and 3,5-diamine-3H-1,2,4-triazole have been synthesized. Full X-ray crystal structure characterizations have been made for all the compounds and the configuration of the structural fragment have been confirmed by the IR-spectra for selected pi-comlexes. The main stereochemichal peсulierities of the obtained pi-complexes have been depicted. Obtained results and revealed peculiarities will be suitable for specialists, employed in copper-catalytic field and crystal engineering. 5 Articles and 2 abstracts of the contributions at scientific conferences have been published. The 4 reports have been made at the conferences.
Product Description
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Миськів Мар'ян Григорович
Мончак Михайло Михайлович
Павлюк Олексій Вікторович
Сливка Юрій Іванович
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2020-04-02