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Information × Registration Number 0211U007622, 0110U005287 , R & D reports Title Supramolecular systems in chemistry and biology. Structure-function relationships in supramolecular systems popup.stage_title Head Andronati S.A., Registration Date 21-07-2011 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 The object of study - 1,2-dihydro-1,4-benzodiazepine-2-ones, molecular clips based on diphenylglycoluryl and benzocrown esters. Crown compounds, halogenated benzo-and Dibenzocrown esters, metal cations. The purpose of the work - the synthesis of 1,2-dihydro-1,4-benzodiazepine-2-ones of molecular clips based on diphenylglycoluryl and benzocrown esters, halogen derivatives of benzo-and dibenzocrown esters to study the structure and complexing properties. A series of 3-acyloxy-1,2-dihydro-3H-1,4-benzodiazepine-2-ones in which aliphatics of residue acyl groups represents a series of Ingold. Thermodynamic analysis of the formation of supramolecular complexes between derivatives of 1,2-dihydro-3H-1,4-benzodiazepine-2-one and benzodiazepine receptors of the cerebral cortex of rats was carried out by the method of radioligand analysis. It have been established that formation of these complexes is regulated by the entropy of a minor and opposite contributions of enthalpy. Product Description popup.authors А. Ляпунов В.И.Павловский Г.Л. Камалов Е. Кулыгина Н. Г.Лукьяненко С. Смульський С.А. Андронати С.А. Котляр С.А. Котляр Т. Кириченко popup.nrat_date 2020-04-02 Close