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Information × Registration Number 0212U002657, 0109U001255 , R & D reports Title The development of the basis of a synthesis, reactivity and stereochemistry of N-, S-heterocycles, O-N-X-geminal systems and quinoneimines for obtaining of compounds with predicted properties popup.stage_title Head Markov Viktor Ivanovich, Registration Date 19-01-2012 Organization State higher educational entity "Ukrainian State University of Chemical Technology" popup.description2 Object of research: the gray-and nitrogen-containing heterocyclic compounds funktsionalizirovanye based tetragidrospiro [cyclohexane-1,2 (1H)-quinazolin] - 4 (3H)-one, N, S-amidoalkiliruyuschih and related reagents, N-arensulfonilarenalaziny-1, 4 - benzohinondiimina and N-atsiloksimetilgeminalnye systems and their equivalents. Purpose: To develop methods for the synthesis of new derivatives of nitrogen-and sulfur-containing heterocyclic compounds based on N, S-amіdoalkiliuyuschih and related reagents, tetragidrospiro [cyclohexane-1,2 (1H)-quinazolin] - 4 (3H)-one, to establish new patterns of heterocyclization processes , investigating the possibilities of synthesis, structure and chemical properties of new types of geminal systems O - N - X (X = O, Cl, N +), the development of methods of synthesis and the establishment of the features of the chemical behavior of new derivatives hinoniminov, the study of reactions of N-аренсульфониларенальазинов-1, 4 - benzohinondiimina with nucleophilic agents. The method of investigation - fine organic synthesis, spectral studies. Based on the original N, S-containing reagents have developed a convenient approach to the synthesis of functional derivatives of 2-thio-6-azatimina and its analogues, 1,3,5-triazine-2-thione, 7H-1 ,3,4-thiadiazole [3,2 - a] [1,3,5] triazine, hydrogenation acridines, which in most cases it is difficult or impossible to obtain by other means. Established theory of the reactions of nucleophilic substitution of chlorine atoms in alkoksigrupi N-derivatives of ureas, carbamates, tert-alkylamines. It is established that 1,4-arenalaziny benzohinondiimina in reactions with nucleophiles hard arenalaziny respond selectively to the 1,8-addition scheme. Industry of use: K 73.10.1 research and experimental development on natural sciences and engineering. Product Description popup.authors Білов Володимир Віталійович Бурмістров Костянтин Сергійович Марков Віктор Іванович Мурашевич Богдан Валерійович Пирогова Любов Миколаївна Просяник Олександр Васильович Руденко Євген Олександрович Саганенко Сергій Анатолійович Сова Світлана Борисівна Строєв Юрій Петрович Торопін Микола Володимирович Фарат Олег Костянтинович Харченко Олександр Васильович Чепишев Сергій Володимирович Штамбург Василь Георгійович popup.nrat_date 2020-04-02 Close