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Information × Registration Number 0212U002868, 0109U001090 , R & D reports Title The influence of composition and structure of 3d metal complexes with N-, O- and S-containing hetero- and macrocyclic polydentate ligands on peroxo-bonds (O-O) formation and decomposition in catalytic liquid-phase oxidation of organic substrates popup.stage_title Head Kamalov Gerbert Leonovich, Registration Date 22-02-2012 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 The kinetics of hydrogen peroxide decomposition in the presence of Co (II) complexes with N,N,N',N' -tetrasubstituted tiocarbamoylsulfenamides and complexes of Co, Ni and Zn with the "chinese lantern" structure containing 2,5- dimethyl- and 2,5-di(trifluoromethyl)- pyrazolate ligands was investigated. The orders of the reaction for H2O2 and catalyst and effective activation energy were determined. A group of isomeric N-oxides of 2-phenyl-1,2,3-triazoles was synthesized and proposed as new ligands Product Description popup.authors Іванов Ю.Е. Грищук Л.В. Д.Є.Степанов Камалов Г.Л. Коцеруба В.А. Краевская Н.С. Левченко О.А. Литвинова Л.В. Чіхічін Д.Г. Яволовський А.О. popup.nrat_date 2020-04-02 Close
R & D report
Head: Kamalov Gerbert Leonovich. The influence of composition and structure of 3d metal complexes with N-, O- and S-containing hetero- and macrocyclic polydentate ligands on peroxo-bonds (O-O) formation and decomposition in catalytic liquid-phase oxidation of organic substrates. (popup.stage: ). A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine. № 0212U002868
1 documents found

Updated: 2026-03-27