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Information × Registration Number 0212U004392, 0109U008221 , R & D reports Title Nano-sized supernucleophilic and oxidative-nucleophilic systems for decomposition of eco-toxicants. popup.stage_title Head Anatolii F. Popov, Доктор хімічних наук Registration Date 09-02-2012 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 Subjects of investigation: organized nano-sized systems (ONS) on the basis of monomeric and dimeric detergents. Physico-chemical properties of ONS, oxidative-nucleophilic decomposition of eco-toxicants in ONS. Research goal: design of the oxidative-nucleophilic systems on the basis of hydrogen peroxide and its activators; design of dimeric detergents, studies on their physico-chemical properties, comparison exsamination of micellar effects of monomeric and dimeric detergents in nucleophilic substitution at phosphorus (V). New systems for decomposition of ecotoxicants. Researh techniques: UV spectrophotometry, IR spectroscopy, conductometry measurements, 1H NMR and 13C NMR studies. Scientific novelty: dimeric detergents at a varied length of spacer and hydrophobic alkyl substintuents with reactive bis-dibromobromate counter ion were first synthesized. Systems on their base are versatile oxidative-nucleophilic systems. Micellar effects in such detergents and their monomeric analogue - cetyltrimethylammonium dibromobromate- were evaluated. Practical significance: usability of the ONS to meet the requirements of "green chemistry" in formulations for utilization/detoxication of ecotoxicants. Application field: environmental protection. Product Description popup.authors Бєлоусова І.О. Бураков М.І. Вахітова Л.М. Гайдаш Т.С. Зубарева Т.М. Капітанов І.В. Карпічев Є.А. Кострикін М.Л. Мітченко О.С. Михайлов В.О. Панченко Б.В. Прокоп'єва Т.М. Разумова Н.Г. Садовський Ю.С. Соломойченко Т.М. Тицький Г.Д. Туровська М.К. Шумейко О.Є. popup.nrat_date 2020-04-02 Close