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Information × Registration Number 0214U000701, 0112U002060 , R & D reports Title Regularities of formation nitrogen- and sulfurcontent heterocyclices. The new rearrangement in conditions of Vilsmeier reaction popup.stage_title Head Markov Victor Ivanovich, Registration Date 14-05-2014 Organization State higher educational entity "Ukrainian State University of Chemical Technology" popup.description2 Object of research – influence of solvent on a course of reaction of cyclization of products of accession of aliphatic amines to arenalazines; inversion of atom of nitrogen in n-alkyl (aryl) - sulfenil-, sulfinil-and derivative sulphonyl imines; 2,2-disubstitution pyrimidine-4-ony and their regrouping in Vilsmayer's reaction; nonsaturated nitriles. The work purpose – to determine consistent patterns of influence of the nature of solvent on a course of reaction of cyclization of products of accession of aliphatic amines to arenalyaziniv-1,4-benzoquinons and quinonediimine; to synthesize acridin and quinoline derivatives; to define requirements to materials as to heterogeneous catalysts of synthesis unsaturated nitrile. Research methods – chemical synthesis, a thin layer chromatography (TLC), the Raystructure analysis (RSA), infrared spectroscopy (IR) and the nuclear magnetic resonance (NMR) - spectroscopy, mass spectrometry. Definitely requirements to materials as to heterogeneous catalysts of synthesis unsaturated nitriles for achievement of high rates of activity and selectivity, a row 2,2-disubstitution pyrimidine-4-onov is received and regularities of a regrouping in Vilsmayer's reaction are considered, is investigated process of inversion of atom of nitrogen in N-alkyl-(aryl) - sulfenil-, sulfinil-and sulfonilpokhidny amines physical and the quantum by chemical methods. Branch of use of results of NIR – C 20.20 production pesticides and other agrochemical production, C 21.10 production of the main pharmaceutical products. Product Description popup.authors Білов Володимир Віталійович Бурмістров Костянтин Сергійович Варениченко Світлана Анатоліївна Залізна (Велика) Катерина Володимирівна Кисельов Вадим Віталійович Куцик-Савченко Наталія Вікторівна Лебідь Олег Сергійович Марков Віктор Іванович Мурашевич Богдан Валерійович Просяник Олександр Васильович Руденко Євген Олександрович Саганенко Сергій Анатолійович Сова Світлана Борисівна Торопін Микола Володимирович Фарат Олег Костянтинович Харченко Олександр Васильович popup.nrat_date 2020-04-02 Close