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Information × Registration Number 0214U008630, 0110U006159 , R & D reports Title N-Aroyl(acetyl)- and N-arylsulphonylbenz(methyl)imidoyl-1,4-benzoquinoneimines. Synthesis and reaction ability. popup.stage_title Head Avdeenko Anatoly Petrovich, Кандидат хімічних наук Registration Date 17-07-2014 Organization Donbass State Engineering Academy popup.description2 Object of research: N-aroyl(аcetyl) -, N-arylsulfonilbenz(methyl) imidoyl-1,4-benzoquinoneimines. Objective of research: an investigation of the process halogenation N-aroyl (аcetyl) -, N-arylsulfonilbenz(methyl) imidoyl-1,4-benzoquinonemonoimines, identification the direction of addition halogen's atom and obtaining halogenderivatives of N-aroyl(аcetyl) -, N-arylsulfonilbenz(methyl) imidoyl-1,4-benzoquinoneimines with the maximum possible number of halogen atoms in quinonoid ring. Research methods: Organic synthesis, elemental analysis data, spectral researches NMR, IR, Х-ray. Theoretical and practical results: As a result of the research the new halogenderivatives of N-aroyl(acetyl)-, N-arylsulfonylbenz(methyl)imidoyl-1,4-benzoquinonmonoimines with alkyl substituents in quinoid ring have been synthesized. For the first the halogenation of methyl group of imidoil fragment was detected. The structures of new compounds were determined by IR, NMR 1Н, 13С spectroscopy and X-ray and element analysis data. Efficiency of introduction: the synthesized compounds can be used in synthetic organic chemistry for synthesis of new p-quinoneimines derivatives and also for the obtaining of new perspective medical preparations. A scope: In the general and special courses of organic chemistry at classical universities. Product Description popup.authors Авдєєнко Анатолій Петрович Гончарова Світлана Анатоліївна Коновалова Світлана Олексіївна Мєнафова Юлія Валентинівна Марченко Інна Леонідівна Санталова Ганна Олександрівна Холмовой Юрій Петрович Юсіна Ганна Леонідівна popup.nrat_date 2020-04-02 Close