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Information × Registration Number 0215U001016, 0112U002060 , R & D reports Title Regularities of formation nitrogen- and sulfurcontent heterocyclices. The new rearrangement in conditions of Vilsmeier reaction popup.stage_title Head Markov Victor Ivanovich, Registration Date 13-01-2015 Organization State higher educational entity "Ukrainian State University of Chemical Technology" popup.description2 Object of research – reactivity of products of reaction of cyclization of aliphatic amines to arenalazines; influence substitute of imines’s atom of Carbon to process topomerization; rearrangments spiroderivatives 1,3-benzoxazine upon treatment Vilsmeier's reagent; synthesis of nonsaturated nitriles with used new catalyst. The work purpose – analysis kinetic investigation of products of reaction of cyclization; determine influence substitute of imines’s atom of Carbon to the size energetic барьера and change of mechanism of topomerization in N-alkyl (aryl) - sulfenil-, sulfinil-and derivative sulphonyl imines; definite rearrangments of rearrangments of spiroderivatives 1,3-benzoxazine upon treatment Vilsmeier's reagent; to define requirements to new inorganic materials as to catalysts of synthesis unsaturated nitrile for achieve of high rates of activity and selectivity. Research methods – chemical synthesis, a thin layer chromatography (TLC), the Raystructure analysis (RSA), infrared spectroscopy (IR) and the nuclear magnetic resonance (NMR) - spectroscopy, mass spectrometry, quantum-chemical calculations. New functional derivatives of 2-amino-5-aryl-1,3,4-oxadiazols, benzimidazoles and benzoxazole based available products of condensation amids of carbon acids with aromatic amines and acylhydrazids. New rearrangements of derivatives of 2-spiropyrimidine-4-ones upon treatment Vilsmeier-Haack reagents which called deep regrouping of carbon skeleton are occur in other systems. Branch of use of results of NIR – C 20.20 production pesticides and other agrochemical production, C 21.10 production of the main pharmaceutical products. Product Description popup.authors Білов Володимир Віталійович Бурмістров Костянтин Сергійович Варениченко Світлана Анатоліївна Залізна (Велика) Катерина Володимирівна Кисельов Вадим Віталійович Куцик-Савченко Наталія Вікторівна Лебідь Олег Сергійович Марков Віктор Іванович Мурашевич Богдан Валерійович Просяник Олександр Васильович Руденко Євген Олександрович Саганенко Сергій Анатолійович Сова Світлана Борисівна Торопін Микола Володимирович Фарат Олег Костянтинович Харченко Олександр Васильович popup.nrat_date 2020-04-02 Close