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Registration Number

0216U001337, 0112U007580 , R & D reports

Title

Syntheses and investigation of physical-chemical properties of metallic nanoclusters with organic sell

Head

Nechitaylov Maxim M.,

Registration Date

05-02-2016

Organization

The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry

Description

The object of study - exohedral metallofullerenes containing transition metals. Purpose - to develop new methods for synthesis of exohedral metallofullerenes, study their composition, structure and properties. Methods of research - organic synthesis, elemental analysis, scanning microscopy, IR spectroscopy. The new method of exohedral metallofullerenes synthesisin organic solutions was developed. It means in the interaction of C60 molecules with "hot" transition-metal atoms (Cr, Fe, Co), generated in situ by reduction of inorganic transition metal salt with sodium borohydride in the presence of phase transfer catalyst (crown ether) was suggested, and with use of organic solvents (toluene, o-xylene). The synthesis of metallofullerenes is accompanied by partial hydrogenation of the fullerene's cage. Obtained metallofullerenes can be used in electric and chemical industry as catalysts of redox and isomerization processes.

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Бондаренко О.В.
Голембіовська О.І.
Демидчук Б.А.
Демченко А.М.
Зябрєв В.С.
Компанець М.О.
Кононець Л.А.
Лукашук О.І.
Міронов О.Л.
Музичка О.В.
Новікова К.В.
Пільо С.Г.
Прокопенко В.М.
Родигін М.Ю.
Труш В.В.
Хайрулін А.Р.
Чумаченко С.А.
Шабликін О.В.