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Registration Number

0216U003769, 0114U003778 , R & D reports

Title

Supramolecular catalysts and nanocontainers: from synthetic surfactants toward bioorganic systems

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Head

Popov Anatolii Fedorovich, Доктор хімічних наук

Registration Date

15-02-2016

Organization

The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry

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Objects of research: organized molecular systems based on different types of surfactants, catalytic processes and molecular recognition of substrates in surfactant-based organized molecular systems. The aim of the study is to design properties of organized molecular systems based surfactants which act as effective nanoreactors and nanocontainers, investigate their properties, and evaluate their potential applications. Research methods: one-dimensional (1 H, 31P) and two-dimensional (1H-1H, 1H-31P) methods of NMR spectroscopy, elemental analysis, spectrophotometry, potentiometry, tensiometry, dynamic light scattering. O the basis of dicationic and monocationic surfactants a number of systems for the selective binding of calix[4]resocinarenes modified at the upper rim with amino acid residues have been elaborated. A biocompatible mixed micellar system based on Twin 80 and oximate functionalized surfactant for efficient cleavage of ecotoxic substrates has been proposed. The technique of synthesis of functionalized surfactants containing boronic acid group has been developed. The abilities to retain selectively model organophosphorus substrates on the polidymetylsiloxane were demonstrated which can be used for designing POC-sensitive layers. The results have scientific importance for the development of the theory of the structure and properties of organized molecular systems. The practical significance of the research is that the resulting system may be applied for selective binding of substrates, designing sensors, and destruction of ecotoxic substrates under conditions similar to the physiological.

Product Description

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Аніщенко Віктор Миколайович
Бураков Микола Іванович
Дикун Олексій Михайлович
Капітанов Ілля Володимирович
Карпічев Євген Адольфович
Мірошниченко Тетяна Миколаївна
Сердюк Ганна Олександрівна

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2020-04-02