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Information × Registration Number 0216U005893, 0112U001196 , R & D reports Title Development of physicochemical bases functionalization of metal nanoparticles to produce different ligands, and organometallic framework metal oxide different nanocomposites popup.stage_title Head Manorik Piter Andreevych, Registration Date 01-03-2016 Organization L. V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of the Ukraine popup.description2 Found that the recovery of nanoparticles (NPs) of metals of the complexes (as precursors) the composition of the latter, their stability, nature of substituents in the ligands are critical factors that determine the size and size distribution obtained are low, the stability obtained colloidal solutions bass suitable for forming nanocomposites. It is shown that the structural and sorption properties and morphology of nanocrystalline TiO2, and sizes of bass Cu, Ag, Au, stabilizing nature of their ligands, as well as crystal and molecular structure of new coordination compounds (CC) 3d- and 4f-metals with aromatic pyridine derivatives, the nature of the central atom and the ligand is critical influence on the photocatalytic, catalytic, photoelectrochemical, sensory properties of these nanocomposites obtained TiO2/M and TiO2/CC. Studied the physical and chemical laws of formation of complexes of cationic and anionic dyes with anionic and cationic surfactants in predmitselyarnomu state obtained ordered .Mesoscopical hybrid organic-inorganic nanocomposite sol-gel film dye / surfactant /TiO2 (SiO2) high, relatively solutions yield fluorescence, effective nonlinear optical properties which are promising for use in optical information systems. The influence of the nature of the reagents and reaction conditions on the peculiarities of redox interaction complexes (MOF) containing tetraaminе cations Ni(II) or Cu(II) and anions Dodeka metalate or octamolybdate (POM) from aqueous solutions of AgNO3 or H[AuCl4], leading to the formation of nanocomposite materials containing nanoparticles of Ag, Au. Ways control the number of metal the size of its bass and their dispersion in these materials. It is established that they are inherent fluorescent properties, which significantly affect the chemical structure and nature POM anions metal (Ag, Au), and demonstrated the possibility of their use as luminescent materials for sensors for nitro compounds. A new method for the synthesis of highly MOF Cu3(BTC)2 and its composites heteropolyacid, the benefits of which are preparative simplicity, high (70%) filling lattice MOF and nearly quantitative yield, and the ability to adapt to synthesize large quantities of the MOF and its nanocomposites controlled bass content of metal in the matrix of the MOF. Product Description popup.authors Гавриш Сергій Павлович Гребєнніков Володимир Миколайович Ермохіна Наталія Іванівна Кишеня Я.В. Лампека Ярослав Дмитрович Леоненко Е.В. Манорик Петро Андрійович Сидорова Наталія Андріївна Сотнік С.А. Тверсков О.Ю. Тельбіз Герман Михайлович Цимбал Людмила Володимирівна Цурупа Ігор Сергійович Шульженко Олександр Васильович popup.nrat_date 2020-04-02 Close