Total number
Full text
Total number
Full text
Number of local repositories
Full text
0216U005893,
0112U001196
,
Development of physicochemical bases functionalization of metal nanoparticles to produce different ligands, and organometallic framework metal oxide different nanocomposites
Manorik Piter Andreevych,
01-03-2016
L. V. Pisarzhevsky Institute of Physical Chemistry of the National Academy of Sciences of the Ukraine
Found that the recovery of nanoparticles (NPs) of metals of the complexes (as precursors) the composition of the latter, their stability, nature of substituents in the ligands are critical factors that determine the size and size distribution obtained are low, the stability obtained colloidal solutions bass suitable for forming nanocomposites. It is shown that the structural and sorption properties and morphology of nanocrystalline TiO2, and sizes of bass Cu, Ag, Au, stabilizing nature of their ligands, as well as crystal and molecular structure of new coordination compounds (CC) 3d- and 4f-metals with aromatic pyridine derivatives, the nature of the central atom and the ligand is critical influence on the photocatalytic, catalytic, photoelectrochemical, sensory properties of these nanocomposites obtained TiO2/M and TiO2/CC. Studied the physical and chemical laws of formation of complexes of cationic and anionic dyes with anionic and cationic surfactants in predmitselyarnomu state obtained ordered .Mesoscopical hybrid organic-inorganic nanocomposite sol-gel film dye / surfactant /TiO2 (SiO2) high, relatively solutions yield fluorescence, effective nonlinear optical properties which are promising for use in optical information systems. The influence of the nature of the reagents and reaction conditions on the peculiarities of redox interaction complexes (MOF) containing tetraaminе cations Ni(II) or Cu(II) and anions Dodeka metalate or octamolybdate (POM) from aqueous solutions of AgNO3 or H[AuCl4], leading to the formation of nanocomposite materials containing nanoparticles of Ag, Au. Ways control the number of metal the size of its bass and their dispersion in these materials. It is established that they are inherent fluorescent properties, which significantly affect the chemical structure and nature POM anions metal (Ag, Au), and demonstrated the possibility of their use as luminescent materials for sensors for nitro compounds. A new method for the synthesis of highly MOF Cu3(BTC)2 and its composites heteropolyacid, the benefits of which are preparative simplicity, high (70%) filling lattice MOF and nearly quantitative yield, and the ability to adapt to synthesize large quantities of the MOF and its nanocomposites controlled bass content of metal in the matrix of the MOF.
Гавриш Сергій Павлович
Гребєнніков Володимир Миколайович
Ермохіна Наталія Іванівна
Кишеня Я.В.
Лампека Ярослав Дмитрович
Леоненко Е.В.
Манорик Петро Андрійович
Сидорова Наталія Андріївна
Сотнік С.А.
Тверсков О.Ю.
Тельбіз Герман Михайлович
Цимбал Людмила Володимирівна
Цурупа Ігор Сергійович
Шульженко Олександр Васильович
2020-04-02
Updated: 2025-12-08
Saving a scientific data set occurs in two stages:
1.) Creating a data set
Enter the name of the set, a brief description of the set (annotation), and click the “Create set” button. After that, a draft data set will be automatically created, which you can save for further work with the set. The system will redirect you to the “Data set information” page.
2.) Filling in the data
On the “Data set information” page, you need to fill in all the fields related to the data set and upload the files.
Please note! Each file is uploaded separately. This is done to ensure the stable operation of the system.
Once you have filled in the information about the scientific data set and added the necessary files, you can save the draft or send the data to the system.
Please note! Once the data has been sent, you cannot change it.
Drafts are necessary for storing the data set and editing it before sending.
All accounts on the NRA website go through a standard registration procedure and are verified. However, in order to obtain additional features, such as publishing open reviews of academic texts, verification by affiliation is required.
To obtain the status “verified”, you must change your primary email address to a corporate one, which is tied to a scientific or educational institution.
For example: user@ukrintei.ua, user@nas.gov.ua
After confirming your corporate email address, your account will be automatically verified by affiliation.
If your email address is corporate, but your account does not have a verification mark, you need to write to us at the email address NRAT@ukrintei.ua. After verification, we will add your address to the database, and your account will be verified.
After completing the verification procedure for affiliation, you can change the primary email address to a convenient one for you, without losing your status during the current verification.
You only need to verify for affiliation once.
* We use corporate addresses from the Unified State Database on Education and the State Register of Scientific Institutions Supported by the State
To search for news published on the official website of NRАT in the “News” section, you need to enter one word, several words, or an exact phrase in the search field. Different terms are separated by spaces.
The search is performed everywhere – in the title and the news text.
For a more comprehensive result, it is recommended to use word stems (parts of words without endings).
When using multiple words for the search, they are combined using one of the logical methods described below.
By default, the logical connector “and” is used. In this case, search results will include all news releases that contain the specified words, even if they are located separately from each other and are in different parts of the text.
Example: Search phrase: OECD report. Search result: all news containing the words “report” and “OECD” in the text and in the title, both together and separately.
If a phrase or phrase is enclosed in quotation marks (“), the results will include all publications where this exact phrase or phrase is found.
Example: Search phrase: “OECD report.” Search result: all news containing the exact phrase “OECD report.”
If you know the publication date of the news or are interested in a specific time frame in which they were published on the website, you can select such a date or date range in the additional field that looks like a calendar. The date is entered in the format year-month-day and confirmed by clicking on the corresponding date in the calendar dropdown. You can enter a date or choose one by browsing through the calendar by months and years. By default, the interval starts from the oldest date (2018-01-23) and ends with the current date.
You can also use one or more hashtags, which are located under the search field on the right side of the “News” page.
Please note: The search for academic texts is carried out in a separate search window at the following link https://nrat.ukrintei.ua/searchdb.
