Registration Number
0216U006260,
0114U001963
, R & D reports
Title
Нomo- and geterometallic complexes of lanthanides with nitrocontaining macroheterocycles: synthesis, structure and luminescent properties.
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Head
Kamalov G.L.,
Registration Date
24-02-2016
Organization
A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine
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Posability of using podands on the basis of bis-[benzimidazolyl-2(1)]alkanes for synthesis 11-18 membered macroheterocycles (MHC) containing two benzimidazole fragments is studied. QSPR research of influence the main factors on fluorescence of studied nitrohalogen-containing hetero- and macroheterocycles and 4f-luminescence corresponding lanthanide complexes is carry out. A good model is constructed and a new approach for registration unstructured factors in QSAR/QSPR models are developed. The complexes of neodymium, ytterbium, lutecium, zinc, cobalt and other metals with modified porphyrines and corroles are obtained. It is shown, that politopnyes structure are liable to react selectively with metals of different nature. For the first time was detected the 4f-luminescence in corroles complexes. It is shown, that the modification of composition and structure of complexes allow to control emission property corresponding luminescence materials. It was found, that emission in all lanthanide-tetrapyrroles can be effectively realize by 4f-radiation and S-S fluorescence of tetrapyrrole.
Product Description
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Єфрюшина Н.П.
Іванов Ю.Е.
А.В. Ляховський А.В.
Камалов Г.Л.
Коровін О.Ю.
Кузьмін В.Є.
Огніченко Л.М.
Русакова Н.В.
Семенішин М.М.
Снурнікова Н.В.
Фадєєв Є.М.
Яволовський А.О.
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2020-04-02
