Registration Number
0217U004499,
0115U006853
, R & D reports
Title
State of organic ions and ionic associates on the surface and in the interlayer gaps of layer silicates as comprehensively studied various methods (adsorption from liquid and vapour phases, calorimetry, X-ray analysis, quantum chemistry).
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Head
Tarasevich Yuri Ivanovych,
Registration Date
03-02-2017
Organization
A.V Dumansky Institute of Colloid Chemistry and Water Chemistry
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Goal of research - to develop the concept of mutual interaction between the elements of modifying layers and the interaction of these elements with bound water. Research objects - adsorbents - natural and modified layer silicates; modifiers - cationic surface-active substances and cationic polyelectrolytes; adsorbates - water, anionic dyes, short-chain surfactants. Methods of research - preparative, calorimetry, structural sorption, spectral, quantum chemical, molecular statistics. Equipment - high-sensitive calorimeter Tiana-Calve Ms-70, spectrophotometer Specord IR-75, personal computer. Theoretical and practical results - the performed microcalorimetric studies of the interaction of short-chain surfactants with the surface of vermiculite have shown that the heat of sorption is determined by two types of interaction. For low coverages the main mechanism is ion exchange, while for higher coverages this factor is complemented by the interaction between the hydrocarbon chains. From the ab initio calculations the energetic and structural characteristics of microclusters formed by the hydration of molecular ions in the water solution, and by the hydration of complex formed by the interaction of these molecular ions in the solution and subsequently sorbed at the surface of layer silicate are determined. Novelty - for the first time the characteristic features of the behaviour of studied systems during the adsorption on the surface of layer silicate. Field of use - environment protection.
Product Description
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Іванова Зінаїда Григорівна
Аксененко Євген Володимирович
Крисенко Дмитро Анатолійович
Трифонова Марина Юріївна
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2020-04-02
