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Information × Registration Number 0220U100850, 0117U002303 , R & D reports Title New complex chalcogenides and halides for non-linear optics, thermo- and optoelectronics: synthesis, structure and properties popup.stage_title Head Olekseiuk Ivan D., Registration Date 28-01-2020 Organization Lesya Ukrainka Eastern European National University popup.description2 The state diagrams of the PbS (Se) –Ga2S (Se) 3 – GeS (Se) 2 systems were first investigated and constructed, in which the formation of the compounds: PbGa2GeSe6 was confirmed and the PbGa2GeS6 compound predicted was revealed. For the first time, the crystal structure of PbGa2GeS6 (noncentrosymmetric PG Fdd2) was established and its crystals were obtained in sizes sufficient for physical measurements. The band structure of PbGa2GeS6, its optical parameters (Eg, transparency region), as well as the generation of the second and third harmonics are established. An incongruent type of formation for the фа-phases existing between the compositions of Pb4Ga4GeS (Se) 12-Pb3Ga2GeS (Se) 8 is established. The Bridgman-Stockbarger method obtained PbGa2GeSe6, Pb2GeS4 crystals. The electronic structure of PbGa2GeS6, PbGa2S4, PbGa2S5, Pb2GeS4, and PbGa6Te10, HgGa2Se4 compounds has been studied by RF and PES methods. The phase equilibrium diagrams of PbGa2S (Se) 4 – SiS (Se) 2 systems, characterized by the formation of compounds of the equimolar composition of PbGa2Si (Ge) X6, were first constructed. Phase equilibria were first investigated in TlGaS2 – Zn (Cd, Hg) S and TlGaSe2 – Zn (Cd, Hg, Fe) Se systems. These systems are eutectic in type with little solubility based on components. For the first time, crystals of TlGa (In) S2: Zn2 + (Cd2 +, Hg2 +) and TlGaSe2: Zn2 + (Cd2 +, Hg2 +) were obtained. Product Description popup.authors Ivashchenko Inna A. Halian Volodymyr V. Zamuruieva Oksana V. Kityk Ivan V. Kadykalo Ella M. Kevshyn Andrii H. Kohut Yurii M. Kozer Vasyl R. Korovytskyi Andrii M. Levkovets Serhii I. Marushko Larysa P. Marchuk Oleh V. Myronchuk Halyna L. Mozoliuk Mariia Yu. Novosad Oleksii V. Olekseiuk Ivan D. Piskach Liudmyla V. Pankevych Volodymyr Z. Parasiuk Oleh V. Piasetskyi Mikhal V. Rudysh Myron Ya. Slyvka Nataliia Yu. Strok Oksana M. Tyshchenko Petro V. Fedorchuk Anatolii O. Fedosov Serhii A. Khyzhun Oleh Yu. Tsisar Oksana V. Shavarova Hanna P. Yurchenko Oksana M. Yanchuk Oleksandr M. popup.nrat_date 2020-04-02 Close
R & D report
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Head: Olekseiuk Ivan D.. New complex chalcogenides and halides for non-linear optics, thermo- and optoelectronics: synthesis, structure and properties. (popup.stage: ). Lesya Ukrainka Eastern European National University. № 0220U100850
1 documents found

Updated: 2026-03-26