Registration Number
0221U102185,
0118U003623
, R & D reports
Title
The oxidation of hydrocarbons and their oxygen-containing oxygen and hydrogen peroxide derivatives to practically important intermediates is evidenced by bio-inspired activators.
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Head
Pokutsa Oleksandr P,
Registration Date
28-01-2021
Organization
Department of Physical and Chemistry of Combustible Fossils LM Litvinenko of the National Academy of Sciences of Ukraine
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The undertaken study exhibits that small additives of oxalic acid significantly decrease the electric resistance of the reaction mixtures constituted with VO(acac)2. Such peculiarity may be the matter of certain enhancement of the oxidation process and aimed products yield at such conditions (was demonstrated at cyclohexane as substrate for H2O2-piloted oxidation in MeCN). On the other hand oxalic acid nullifies the effect of NHPI due to quick destruction (hydrolysis) of the last promoter.
Study the oxidation of acrydine by peroxydecanoic acid in different organic solvents led to conclusion that most important parameter of the solvents regarding it influence on the process rate was polarity (B). Whereas impact of δ2 and Еt was much more lower. Such correlations were preserved within the whole tested temperature interval.
Product Description
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Balashova Iryna Ye
Dutka Volodymyr S
Zaborovskiy Andriy B
Kubay Yuliya Yu.
Midyana Halyna H
Maksym Dariya S
Fedas Nataliya V
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2021-01-28
