Registration Number
0223U002092,
0120U102028
, R & D reports
Title
Controlled synthesis, structure and properties of copper-containing homo- and heterometallic compounds for optoelectronics
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Head
Pavlyuk Oleksiy V, Кандидат хімічних наук
Registration Date
09-02-2023
Organization
Ivan Franko National University of Lviv
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Report on the scientific project: 129 pages, 22 figures, 73 tables, 65 sources.
ALLYL DERIVATIVES, ADENINE, BENZIMIDAZOLES, BENZOTRIAZOLES, CRYSTAL STRUCTURE, PYRIDINES, UREA, THIOHYDANTOIN, THIODIAZOLES, THIOMORPHOLINE, TETRAZOLES.
Object of the study: the peculiarities of formation and crystal structure of homo- and heterometallic copper-containing compounds with allyl-substituted organic ligands.
The purpose of the work is to establish the regularities of "composition-structure-properties" for new copper-containing homo- and heterometallic compounds.
Research methods: single crystal and powder X-ray diffraction, UV/Vis-, IR-, NMR spectroscopy.
For the first time, a number of organic ligands (based on thiohydantoin, tetrazole, adenine, triazole, cyanopyridine, benzotriazole, benzimidazole, thiomorpholine, etc.) were synthesized and 19 new crystalline complexes based on copper (or REE) were obtained. For 20 compounds, a complete solving and refinement of the crystal structure model was carried out using the single crystal X-ray method. The main features of the crystal structure of the obtained compounds were established.
The obtained information will be useful for specialists working in the field of cuprocatalysis and crystal engineering.
One dissertation of the Doctor of Chemical Sciences was defended. Three master's theses have been defended, 16 articles, 2 patents, 1 monograph were published.
Product Description
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Zelinskyy Anatoliy V.
Luba Alona Oleksandrivna
Pavlyuk Oleksiy V.
Slyvka Yurii Ivanovych
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2023-02-09
