Registration Number
0310U002743,
0106U001144
, R & D reports
Title
New molecular receptors and supramoleculars of catenanes and rotaxanes types: synthesis, structure and properties.
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Розробка методів синтезу нових молекулярних "пінцетів", що містять фрагменти краун-ефірів, вивчення їх структури і спектральних властивостей.
Head
Lukyanenko N.G,
Registration Date
08-06-2010
Organization
A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine
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A research object is derivativates of diphenylglycoluril, containing the fragments of benzocrown ethers. The methods of synthesis of new class of molecular clips are developed on the basis of diphenylglycoluril, containing as donor centers fragments of benzocrown ethers. The row of compounds of this type, the structure of which is proved spectral methods and X-ray analysis, is received. It is set that in the crystalline structure of compound on the basis of benzo-15-crown-5 the molecule of chloroform, which is located directly in the cavity of molecular pincers, is included. Unlike it similar compound, containing the fragments of benzo-12-crown-4, does not include some substrate in the cavity. However, there are molecules of chloroform and water in a crystalline grate.
Product Description
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Богащенко Т.Ю.
Кириченко Т.І.
Кулигіна К.Ю.
Лобач О.В.
Лук'яненко Микола Григорович
Ляпунов О.Ю.
Пастушок В.М.
Яковенко І.С.
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2020-04-02
