Registration Number
2197U000140, Article
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Текст
Title
Electrochemical process at the Cu6PS5I-electrolyte interface (AI translated)
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Стасюк Юрій Михайлович
Ковач С. К.
Кохан Олександр Павлович
Панько В. В.
Stasiuk Yurii Mykhailovych
Kovach S. K.
Kokhan Oleksandr Pavlovych
Panko V. V.
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01-01-1997
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Ужгородський національний університет
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https://dspace.uzhnu.edu.ua/jspui/handle/lib/42260
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Поличка "Карпатського краю"
Description
Cu6PS5I and Cu6PS5Br single crystals were grew bу chemical vapor transport method in а closed silica tube. The copper-selective electrodes based on there materials were obtained. The Nernstian response of the electrode remains in the range of concentratiqp. 10-1-10-5 M CuSO4 and thе slope was 27±2 mV /decade. The current-voltage investigation demonstrate that the Cu6PS5I- electrode behaved as the p-type semiconductor. Cyclic voltammogram of the Cu6PS5Br electrode showed the processes to bе relation tothe motion of copper-ions in solid phase and to intercalation of Cu+2 from solution to crystal.
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2026-06-13
