Registration Number
2120U011180, Article
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Стаття
Title
Synthesis, structure and application of mixed-ligand coordination compounds of copper(ІІ) with substituted thioamides
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Ranskiy A.
Gordienko O.
Didenko N.
Titov T.
Khutko M.
Ranskiy A.
Gordienko O.
Didenko N.
Titov T.
Khutko M.
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01-01-2020
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Вінницький національний медичний університет ім. М. І. Пирогова
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https://dspace.vnmu.edu.ua/123456789/5378
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Description
New coordination compounds of copper(II) with substituted thioamides of the general formula [Cu(HL6-9)2X2]2 and CuL2 6-9 have been synthesized. The consecutive reaction of nucleophilic substitution/elimination of SN 1 /E1 in the octahedral complex [Cu(NH3)4Cl2]·H2O and catalytic hydrolysis of [Cu(HL6-9)2X2]2 complexes have been investigated. Using IR spectroscopy, elemental and XRD analysis, the composition and structure of the synthesized complexes have been determined. The molecular and crystalline structure of the complex [Cu(C30H26Cl2N6O8S2)]·i-C3H7ON was determined by X-ray diffraction analysis. The tribotechnical characteristics of some coordination compounds as additives to industrial oils have been investigated.
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2026-09-16
