Registration Number
0203U006026,
0101U001082
, R & D reports
Title
Investigation of possibility to synthesize bis-crown-ethers with ethylene fragment in birding chain.
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Head
Lukyanenko N.,
Registration Date
05-02-2003
Organization
A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine
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Synthesis of monobenzocrown ethers in two phase systems liquid-solid and liquid-liquid has been investigated. Application of Baier reaction for the synthesis of stilbene crown ethers has been studied. Complexes with content metal-ligand 2:1 or 1:1. With potassium and rubidium cation have been formed depending on the configuration of stilbene fragment. Molecular modeling within the frames of molecular mechanics demonstrates that sandwich complexes are mainly formed in case of large cations and ligand excess.
Product Description
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2020-04-03
