Registration Number
0211U004196,
0110U003510
, R & D reports
Title
Di- and polynuclear pyrazolate-carboxylates of the transition metals as catalysts for liquid-phase oxidation of substrates with activated C-H bonds
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Head
Kamalov Gerbert Leonovich,
Registration Date
26-01-2012
Organization
A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine
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The kinetics of hydrogen peroxide decomposition and dibenzyl ether (DBE) liquid-phase oxidation in the presence of 3d metals complexes was investigated. Main routes of the reaction and influence of the composition and structure of the initial complexes on the selectivity and conversion of DBE were defined. Characteristic of the hydrogen peroxide decomposition's kinetics in the presence of cobalt and copper carboxylate and carboxylate-pirazolate complexes was given. Polyfunctional nitrogen-containing heterocycles - potential ligands for modeling of the coordination sphere of natural metaloenzymes were synthesized
Product Description
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Іванов Ю.Е.
Грищук Л.В.
Камалов Г.Л.
Коцеруба В.А.
Левченко О.О.
Степанов Д.Є
Чіхічін Д.Г.
Яволовський А.О.
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2020-04-02
