Registration Number
0212U002870,
0111U002397
, R & D reports
Title
New ligands are based on 2-( beta-oxoalkyl)-pyrimidin-4(3H)-ones and their complexes with 3d metals
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Head
Yavolovskii A.A.,
Registration Date
22-02-2012
Organization
A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine
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Starting material and intermediates of 2-thiouracils and their products of S-alkylation by alfa-halogenketones were synthesized. The synthesis methods of 2-(2-oxoalkyl)pyrimidines by desulfurization of 2-(2-oxoalkyltio)pyrimidines with triphenylphosphite in boiling dimethylformamide were developed. It is established that 2-(2-oxoalkyl)pyrimidines in solution have structure of enaminketones, which are in the form of a mixture of E, Z-isomers.
Product Description
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Грищук Л.В.
Иванов Ю.Э.
Коцеруба В.А.
Левченко О.А.
Степанов Д.Е
Чихичин Д.Г.
Яволовский А.А.
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2020-04-02
