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Information × Registration Number 0212U002870, 0111U002397 , R & D reports Title New ligands are based on 2-( beta-oxoalkyl)-pyrimidin-4(3H)-ones and their complexes with 3d metals popup.stage_title Head Yavolovskii A.A., Registration Date 22-02-2012 Organization A.V.Bogatsky Physico-Chemical Institute of the National Academy of Sciences of Ukraine popup.description2 Starting material and intermediates of 2-thiouracils and their products of S-alkylation by alfa-halogenketones were synthesized. The synthesis methods of 2-(2-oxoalkyl)pyrimidines by desulfurization of 2-(2-oxoalkyltio)pyrimidines with triphenylphosphite in boiling dimethylformamide were developed. It is established that 2-(2-oxoalkyl)pyrimidines in solution have structure of enaminketones, which are in the form of a mixture of E, Z-isomers. Product Description popup.authors Грищук Л.В. Иванов Ю.Э. Коцеруба В.А. Левченко О.А. Степанов Д.Е Чихичин Д.Г. Яволовский А.А. popup.nrat_date 2020-04-02 Close