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Information × Registration Number 0203U008369, 0100U003728 , R & D reports Title Investigation of phase transitions and critical phenomena on the base of a new Fluctuational Equation of the State in binary solutions, which contain the polymer components popup.stage_title Head Rogankov V.B., Доктор фізико-математичних наук Registration Date 11-11-2003 Organization The Odesse state acasemy of refrigeration popup.description2 The critical curve conditions are represented as the system of algebraic equations, based on the fluctuation equation of state. The calculation-graphic method of solution is developed which provides the reasonable consistence with the experimental data. The method can be applied to the prediction of critical phenomena and global phase diagram in mixtures contained a polymer component. Thermodynamic consistency is an important condition for the global phase diagram's prognosis as it has been demonstrated. The concept of internal energy and entropy term's superposition was used in the building of the fluctuation equation of state instead of usual superposition of the repulsive and attractive term's. The entropy term has a great influence on description of the polymer components properties. Product Description popup.authors popup.nrat_date 2020-04-02 Close