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Information × Registration Number 0211U001203, 0109U006369 , R & D reports Title 3. Nanocatalysis of organic reactions: development of carbene and metalcomplex nanocatalysts and their use in the reactions of С-С and С-Heteroatom bond formation. popup.stage_title Head .Shvaika Oles Pavlovitsh, Registration Date 25-01-2011 Organization Donetsk National University popup.description2 3. Nanocarbene palladium complexes of 1,2,4-triazole-5-ylidenes, pyrazoline-5-ylidenes were synthesized by direct ac-tion of palladium and other transition metal salts to individual carbenes. Polymer palladium, silver and nickel car-bene complexes were prepared on the bases of crown-biscarbenes and 3,3'-bridged bis-1,2,4-triazole-5-ylidenes. Pal-ladium chelated heteroaromatic complexes of 1,2,4-triazole series were obtained. A stable carbene of the pyrazole series was synthesized for the first time for further complex formation. Polyquaternization of imidazoles was also ac-complished to achieve macrocyclic carbene systems. Product Description popup.authors Кисельов Артем Вікторович Коротких Микола Іванович popup.nrat_date 2020-04-02 Close