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Information × Registration Number 0211U007854, 0107U006216 , R & D reports Title Сhemiluminescence in the reactions of the peroxide radicals. popup.stage_title Head Koval Zinoviya, Registration Date 13-10-2011 Organization Lviv Polytechnic National University popup.description2 Object of investigation: azoisobutyronitrile, lauril peroxide. Subject of unvestigations: peculiarities of chemiluminiscence in peroxide radical reactions. Work aim: investigation of peculiarities of chemiluminiscence in reactions of formation and termination of free radicals, determination of quantity characterisyics of these processes, investigation of influence of natire conditions on their proceeding. . Investigation methods: chemiluminiscent and preparation chemical methods of analysis were used at investigation of kinetics of initiator decomposition in liquid phase reactions. Gasometric and kinetic methods of investigations were used for characteristic of reaction activityof molecules and free radicals, determination of the rates of elementar reactions of the process of formation and termination of free radicals, . Method of inhibitors was used for investigation of peculiarities of radical formation. Using of investigation: General kinetic equations were proposed used for interpretation of reactions of formation and termination of free radicals. Obtained experimental results wide the theory and practice of homolytic free radical reactions that are need for creation of theoretical base of mechanism of lenth termination, condition role in free radicalreactions of oxidation and for determination reaction activity of molecules and free radicals. Key words: Chemiluminiscence, homolitic free radical reactions, initiator, evolving of radicals from cell. Product Description popup.authors Коваль Зіновія Мирославівна popup.nrat_date 2020-04-02 Close