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Information × Registration Number 0213U002100, 0111U005921 , R & D reports Title The development of new methods of syntheses, structure and properties investigation of exohedral metallofullerenes containing transition metals popup.stage_title Head Nechitaylov Maxim M., Registration Date 15-01-2013 Organization The L.M.Litvinenko Institute of Physical-Organic Chemistry and Coal Chemistry popup.description2 Subject of investigation is exohedral metallofullerenes contained the transition-metals; the purpose of investigation is development of new method of metallofullerenes synthesis and study of they composition, structure and properties. Investigation’s methods are organic synthesis, scanning electron microscopy, dispersion energy analysis and IR spectroscopy. The developed method of synthesis based on the interaction of C60 with the transition-metal atoms, generated in situ by the reduction of transition metal salts by sodium borohydride, with the presence of crown ether in the organic solvent. This method of synthesis make it possible obtain of metal-fullerene complexes, which may be use as magnetic materials in instrument engineering, and also in organic synthesis as catalysts of isomerization and red-ox reactions Product Description popup.authors Кисельова Ольга Леонідівна Невечеря Оксана Іванівна popup.nrat_date 2020-04-02 Close