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Information × Registration Number 0217U000832, 0114U001377 , R & D reports Title Study of peculiarities of fullerenes formation and their interaction with molecules of solvents popup.stage_title Head Schur Dmytro, Registration Date 10-03-2017 Organization Frantzevich Insitute for Materials Science Problems of the Ukranian National Academy of Sciences popup.description2 The paper studied the possibility of fullerenes synthesis in three ways: by pyrolysis method, by arc synthesis in the gas phase, and by arc synthesis in liquid phase. It is recognized that the method of synthesis by arc in the gas phase remains the only cost-effective for the synthesis of spherical molecules. The features of fullerenes dissolving have been studied and the model of fullerene molecules C60 existing in solution has been proposed. The method of calculating the solubility of C60 in substituted aromatic hydrocarbons is developed, and it is shown the correlation between C60 solubility and mesomeric effect of substituting groups in benzene solvents. It is discovered the "ordering effect of meta-nitro isomers". It is revealed that fullerene C60 solubility in monosubstituted benzenes with donor groups is directly proportional to the sum of the concentrations of ortho- and para-nitroizomers. For the first time it is found that the positive and negative mesomeric effects in monosubstituted benzenes are directly proportional to the sum of ortho- and para-nitro izomers concentrations. Product Description popup.authors Боголєпов В,ячеслав Олексійович Золотаренко Анатолій Дмитрович Золотаренко Олексій Дмитрович Золотаренко Олександр Дмитрович Копилова Людмила Іларіонівна Кривущенко Ольга Яківна Матисіна Зінаїда Альфредівна Шапошнікова Тетяна Іллівна Щур Дмитро Вікторович popup.nrat_date 2020-04-02 Close