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Information × Registration Number 0221U000138, 0119U100712 , R & D reports Title Mechanisms of catalytic action of polynuclear complexes and carbon nanoclusters in reactions of homogeneous oxidation of organic substances popup.stage_title Head Polunkin Yeugene V., Кандидат хімічних наук Registration Date 02-01-2021 Organization V.P. Kukhar Institute of Bioorganic Chemistry and Petrochemistry of the National Academy of Sciences of Ukraine popup.description2 Modern ideas about possible mechanisms of transformation of molecules of liquid hydrocarbon motor fuels at different stages of their oxidation and combustion depending on temperature conditions are considered. Diffusion limitations in the combustion of fuel droplets in reaction volumes and the negative effect on the completeness of combustion of the micelle formation effect by primary polar oxidation products (alcohols, aldehydes, ketones, etc.) in the liquid hydrocarbon phase of motor fuels are highlighted. The possibility of blocking unwanted micelle formation in liquid fuel droplets due to the local ordering of polar fuel molecules around the additives of fullerene-type nanoparticles is substantiated. The influence of a number of polynuclear complex compounds and nanosized carbon clusters on the initiated liquid-phase oxidation of model components of motor fuels at low temperatures has been experimentally studied. It is shown that the synthesized metal complexes and fullerenes under the investigated temperature conditions inhibit the oxidation of hydrocarbons and alcohols. Product Description popup.authors Bereznitskiy Yaroslav O. Bogomolov Yuriy I. Gayday Olga О. Kameneva Tatiana M. Melnykova Svіtlana L. Pyliavsky Volodymyr S. Starzhynska Ludmila І. popup.nrat_date 2021-01-02 Close