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Information × Registration Number 0221U105320, 0120U102179 , R & D reports Title Methodology for production and use of organic synthesis intermediates based on catalytic processes involving industrial gases. popup.stage_title Head Riabukhin Serhii V., Доктор хімічних наук Registration Date 25-06-2021 Organization Taras Shevchenko National University of Kyiv popup.description2  Object of research: Catalysts and composites based on available non-toxic metals, low molecular weight organic intermediates, building blocks for the synthesis of substances with useful properties, industrial gases. The aim of the project is to establish the factors that determine the catalytic activity of composites based on graphene, graphene-like materials, 3d-metal compounds in the processes of hydrogenation, oxidation, carbonylation and carboxylation of organic compounds using CO and CO2, and CH-activation of C1-C4 alkanes. their transformation into carbon and boron acids; creation of effective catalysts for such processes and development of a methodology for carrying out these reactions that will meet the requirements of green chemistry; use of developed procedures for the synthesis of useful intermediates and building blocks for the needs of medical chemistry. Research methods: LCMS spectroscopy, gas GCMS spectroscopy, NMR spectroscopy on 1H, 13C, 19F, 2D NMR spectroscopy (NOESY, COSY, HMBC, HSQC), elemental analysis and X-ray diffraction analysis of single crystals. Catalysts based on cobalt and nickel were obtained, which are not inferior in their catalytic activity to composites containing precious precious metals (platinum or palladium). To obtain composites based on graphene and graphene-like materials, we used the methodology developed by us for pyrolysis of metal-containing compounds with the simultaneous formation of metal-containing graphene. Complex compounds of the corresponding metals with melamine, para-diaminobenzene, phenanthroline were used as starting materials to obtain the desired composites. Among more than 10 catalytic systems based on the results of testing for quinoline hydrogenation reactions, the ones that showed the best results were selected as a model. Product Description popup.authors Volochnyuk Dmitro M. Grabchuk Galyna P. Kolotilov Sergey V. Lyapunov Alexander Yu. Makhankova Valeriya H. Nosyk Pavlo S. Ostapchuk Evgen M. Pashchenko Oleksandr Ye. popup.nrat_date 2021-06-25 Close