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Information × Registration Number 0310U002567, 0105U005668 , R & D reports Title The investigation of the structure, reactivity and catalytic activity of coordination compounds of 3d-metals with acido ligands, amines and derivatives of their condensation popup.stage_title Дослідження активності комплексів Со(ІІ), Mn(II), Cu(II) і Pd(II) в реакції розкладу пероксиду водню та оксинення монооксиду вуглецю Head Rakitskaya Tatyana, Доктор хімічних наук Registration Date 05-05-2010 Organization Odessa I.I. Mechnikov National University popup.description2 The kinetics of hydrogen peroxide decomposition by aerosil-immobilized ligands: aminopropylaerosil (APA), salicylalimine (Sal), o-vanillin (o-Van) and p-vanillin (p-Van) has been studied. It has been stated o-Van to show the least activity and Sal to show the greatest one. The activation energy changes in the same way. The kinetics of hydrogen peroxide decomposition by Cu(II), Co(II), and Mn(II) complexes with aerosil-immobilized APA, Sal, o-Van, p-Van has been studied. It has been stated the ligands nature essentially doesn't influence essentially on complexes activity, and the reaction to proceed by chain-radical mechanism. It has been shown at reuse Mn(II) complexes to reveal rather high activity in hydrogen peroxide decomposition reaction. The influence of ligands nature (fluoride, chloride, bromide, sulfate) on kinetics of carbon monoxide oxidation by oxygen in the presence of Pd(II)-Cu(II)/support (natural zeolite) has been studied. It has been shown when bromide-ions concentration in catalyst composition increased its activity passed maximum and in the case of fluoride, chloride, sulfate-ions the activity decreased abruptly. Product Description popup.authors Гриценко І.С. Кокшарова Т.В. Курандо С.В. Труба А.С. popup.nrat_date 2020-04-02 Close