Реєстраційний номер
2117U008817, Матеріали видань та локальних репозитаріїв
Категорія
Текст
Назва роботи
Spectrophotometric and theoretical studies of the protonation of Allura Red AC and Ponceau 4R
Автор
Бевзюк Катерина
Чеботарєв Александр
Снігур Денис
Базель Ярослав Рудольфович
Фізер Максим Михайлович
Сідей Василь Іванович
Bevziuk Kateryna
Chebotariev Aleksandr
Snihur Denys
Bazel Yaroslav Rudolfovych
Fizer Maksym Mykhailovych
Sidei Vasyl Ivanovych
Дата публікації
12-07-2017
Постачальник інформації
Ужгородський національний університет
Першоджерело
https://dspace.uzhnu.edu.ua/jspui/handle/lib/15977
Видання
Elsevier
Опис
The acid-base properties of Allura Red AC and Ponceau 4R azo dyes were investigated by spectrophotometric, potentiometric and tristimulus colourimetry methods. Ionization constants of the functional
groups were also found in aqueous solutions of the dyes. It was discovered that the wavelength of the
maximum light absorption of Allura Red AC and Ponceau 4R solutions does not change significantly over
a wide pH range. As a result, spectrophotometric methods yield little information for assessing the acidbase properties of the dyes. It was shown with a help of the tristimulus colourimetry method that it is
possible to determine the ionization constants of the functional groups of the dyes even when there is
significant overlap of the absorption bands of the acid-base forms. The basic spectrophotometric characteristics of the main forms of Allura Red AC and Ponceau 4R in water and organic solvents were
calculated. The molar absorbance coefficients of azo forms were shown to increase as the dielectric
permittivity of the solvent increases. It was determined that in aqueous solution the dyes exist in the azo
form over a wide range of acidity e pH 2e12 for Allura Red AC (lmax ¼ 505 nm;
εl ¼ 3.1$104 dm3 mol 1 cm 1) and 1e13 for Ponceau 4R (lmax ¼ 510 nm; εl ¼ 1.7$10 4 dm3 mol 1 cm 1).
The most probable protonation/deprotonation schemes were theoretically determined for Allura Red AC
and Ponceau 4R using DFT calculations.
Додано/оновлено в НРАТ
2026-06-13
