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Information × Registration Number 0215U003762, 0110U003782 , R & D reports Title Physicochemical bases of synthesis and spectral-structural characteristics of different functional nanoscale d-metals coordination compounds with heterocyclic bioligands - hydroxyiminothiazoles, thioureas and hydroxyiminoacetates popup.stage_title Head Pekhnyo Vasyl Ivanovych, Registration Date 24-03-2015 Organization National Academy of Scienіses of Ukraine, Council of Productive Forces Studies of Ukraine popup.description2 The 28 new coordination compounds of transition metals (Ru, Rh, Pd, Pt, Cu, Zn) based on functionally thioureas and hydroxyiminothiazoles has been synthesized and spectral investigated. The peculiarities of these ligands in coordination complexes have been studied depending on the geometric arrangement of the donor or acceptor substituents in their molecules. The extraction-photometric methodic of determination and separation of Ru, Rh, Pd in the joint presence in model solutions of their chlorides has been developed, which is important for the processing of raw materials containing platinum metals. Antitumor effects of test compounds (Cu(II) and Pd(II) complexes based on hydroxyiminoacetates) on malignant cells have been established, making them promising to develop a new generation of anticancer drugs. It has been established that palladium complexes are nano-objects: nanotube at molar ratio M:L = 1:1 and nano fibers at M:L = 1:2 with a diameter from 25 to 100 nm. It was published in 9 articles and 6 theses. Product Description popup.authors Бонь Володимир Васильович Орисик Світлана Іванівна Репіч Гліб Геннадійович popup.nrat_date 2020-04-02 Close